"IIS-RT"-1999. Collection №15-12 |
Noncontact electrochemical water activation
experiments V.G. Shironosov, Е.V. Shironosov Scientific
Research Center "IKAR", ikar.udm.ru,
ikar@udm.ru
Scientific Research Center "Resonant Technologies" Udmurt State University,
http://v4.udsu.ru/science/untsrt
The II International Symposium "Electrochemical Activation
(ECA) in medicine, agriculture economy, industry". М.: October 28-29
1999, p.68. Results
of the water ECA experiments are given. Simple model, explains the noncontact
activation, are suggested. Electrochemical activation, theoretical physics.
The noncontact electrochemical water
activation phenomenon (CAW) was theoreticaly predicted in 1992 on the base of
substantial field physical theory by I.L. Gerlovin [1]. Noncontact ECA experimental
results was published by V.М. Bahir in 1992 [2]. Hermetically
sealed thin-walled capacitys (ampoules or capsules), or a polyvinyl chloride tube
(PVC, diameter - 3 mm, thickness of the wall - 1 mm) with physiological solution
was placed to the work chambers of (anodic or cathodic) electrochemical diaphragmal
activator. As a rule, activation of the ampoules was conducted for 30 minutes
by switched on current or by current switched off immediately before placing of
the capacitys with physiological solution to ECA mediums. After
30 minutes of noncontact activation results to the solutions in the ampoules was
[3]: Table. Parameters | Initial
physical sol. | Anolyte | Catholyte | D
LA C:off D LA C:on | D
GA C:off D GA C:on | D
FA C:off D FA C:on | D
LC C:off D LC C:on | D
GC C:off D GC C:on | D
FC C:off D FC C:on | рН | 6.7±0.2 | 1.1 | 11.5 | -0.8±0.1
-1.3±0.1 | -0.2±0.1 -0.5±0.1 | 0.1±0.2
0.2±0.15 | 0.5±0.2 0.8±0.2 | 0.2±0.15
0.4±0.2 | -0.4±0.1 -0.2±0.1 | ORP,
мВ | 260±5 | 1135±15 | -845±5 | 110±10
150±7 | 31±8 30±5 | -80±5 -130±4 | -490±7
-560±10 | -280±5 -370±6 | 23±7 30±10 |
where, D
LA current:off = рН(ORP)la C:off-рН(ORP)initial ph. sol.; L,G,F - matherial of
the ampoule (lavsan, glass, fluoroplastic); А - anolyte activation, C - catholyte
activation, C:off(on) - activation by current swithed on(off) immediately before
placing the capacitys with physiologicl solution to ECA mediums. In
that way, after exposition of hermetical ampoules with the physiological solution
in anolyte or in catholyte, the results рН and ORP of physiological solution was
materially changed; it could be regarded as displaying of the noncontact ECA.
The effect is the same when the electrolizer is switched on or when it is switched
off. Anolyte and catholyte are influence on the physiological solution though
the glass, lavsan and fluoroplastic. By that, the direction of the pH and ORP
changes corresponds (for the glass and lavsan) to sign of electrochemical processing
(anodic or cathodic) and inverts for the fluoroplastic. In 2 hours after ECA,
the pH and ORP results are relaxing; it is the evidence of electrolize stable
products unpenetration into hermetically sealed thin-walled capacitys. Therefore,
noncontact ECA passes on an energetic level without any attendant transport (mass
exchange) of ions through the ampoules wall[3]. We
conducted complementary experiments for elucidation of the noncontact activation
phemomenon nature. Experiment 1: Hermetically sealed thin-walled
polyethylene packets (thickness of the pellicle ~0.1 mm) with distilled water
placed into a work cathodic chamber of the electrochemical activator "Espero-1".
Activation was conducted with a diaphragm and without it for 30 minutes by switched
on current. The results are in the table 1. Table 1.
Parameters | Initial
distilled water | medium cathod with
diaphragm | cathod medium without diaphragm | Dpacket
with diaphragm | Dpacket
without diaphragm | рН | 7.2±0.2 | 10.7 | 7.6 | -0.4±0.2 | -0.4±0.2 |
ORP, мВ | 264±5 | -873±5 | -460±5 | -364±20 | -384±20 |
where, D pac with
diaph.=рН(ORP)pac. without diaph.-рН(ORP)init. dist. water Experiment
2:Hermetically sealed thin-walled polyethylene packets (thickness of the pellicle
~0.1 mm) with distilled water placed into cylindrical food aluminium and plastic
capacitys (dalum14=14 sm, dplast14=14 sm), filled with catholyte.
Catholyte (рН=13.5, ORP = -950 мВ) was received on the "Emerald-Si"
unit. Activation was conducted for 30 minutes in fresh-made solutions. The results
are in the table 2. Table 2. Parameters | Init.
dist. water | D
alum14 | D alum+polyeth14 | D
alum+tefl14 | D
alum14+plast | D
plast14 | D plast+foil14 |
рН | 7.5±0.2 | -0.3±0.2 | 0±0.2 | -0.8±0.3 | -0.4±0.3 | -0.4±0.3 | 0.3±0.3 |
ORP,мВ | 289±3 | -749±10 | -245±10 | -301±10 | -175±10 | -165±15 | -280±15 |
where, D х =рН(ORP)х-рН(ORP)init.
dist. water, alum+polyeth14 -catholyte was filled into a thin polyethylene packet
(~0.1mm), wich was close-adjoined to aluminium capacity walls, alum+tefl14 - aluminium
capacity with a thin-walled teflon cover, alum14+plast - catholyte was filled
into a plastic capacity (thickness of the wals ~2 mm) and placed into an aluminium
capacity-alum14, plast+foil14 - the thin aluminium foil was close-adjoined to
the plastic capacity walls. Experiment 3: Dielectrical vessels with
anolyte and catholyte( V = 100 ml.), were prepared on the "Emerald-Si" unit by
Va=Vk =5 l/hour, placed into micro wave field (Р = 1 КВт, n=2.4 ГГц) for 1 minute,
after that its parameters were measured. Measuring of the parameters and heating
of the anolyte and catholyte was simultaneously conducted for 1-2 minutes in the
water bath. The results are in the table 3. Table 3.
Parameters | Initial
solutions | Micro waves | Heating |
anolyte | catholyte | anolyte | catholyte | anolyte | catholyte |
РН | 3.9 | 12.4 | 3.0 | 13.1 | 2.7 | 13.0 |
ORP,мВ | 1108±10 | -960±10 | 1093±10 | -253±10 | 1085±10 | -928±5 |
Т, degree С | 22±0.1 | 22±0.1 | 50±2 | 50±2 | 50±2 | 50±2 |
The experiments permit to draw some conclusions:
- The noncontact electrochemical water activation are to be observed by
small thickness of dielectric partition (mm and less) and depands from a matherial
of the partition; by that, CAW, in anodic and cathodic chambers, has a different
sign of D ORP (table) for the same matherial partition;
- CAW takes place as for ECA water with diaphragm as for ECA water without it
(table 1);
- DORP increases by activation in a metal
capacity, or in a metal capacity with a thin nonconductive dielectrical cover
(table 2)
- Nonthermal influence effect of microwave field to the catholyte
(sharp decreasing of ORP table 3).
Anomal properties
1-3 phenomenon of noncontact electrochemical activation can be simply explained
by origin of highenergetics steady resonance systems from ascillating water difields,
ОН- (two and more) near the anode and cathode [4-7]. In statics such
systems from difields are not steady (collaps effect), in dynamics, by resonance,
a dynamics stabilisation unsteady condition effect displays though [5-7]. Variable
electromagnetic field from two synchronously-ascillating difields (SAD) [6] has
a narrow frequency spectrum (resonance effect and decrease ~ 1/r6.
Maximum of the spectrum, possibly, belong to microwave diapason, because, for
ОН- typical frequencies of rotation transitions ~2 ГГц (length of a
wave lо =18 sm). Therefore, contactlass activation can to be origin
only from thin walls, close by SAD, and depend from spectral properties of matherial-partition.
Amplification of CAW in metal cylindrical form capacitys can be explained by amplification
of active microwave field by means of reflection from the conducting surfaces
(microwave resonator effect). It should be expect amplification of CAW by the
sizes ofcapacityes ~l о, l
о/2. Literature - Gerlovin I.L. The base of the
united theory of all interaction in a matter .-SP.; Energoatom Publication 1990
- Bahir V.М. Electrochemical activation. -М.; ARSRIMT, v.1, 1992. p. 197-204.
- Prilucky V.I., Bahir V.М. Electrochemical activated water: Anomal properties,
mechanism of biological action.- М.; ARSRIMT JS Scientific Production Unity "Ecran".
1997. -p. 228.
- Shironosov V.G. Physical base of resonance activation of water,
p. 220-221, The I International Symposium "Electrochemical activation in,
medicine, agriculture economy, industry ", collection of the articles -M;
ARSRIMT JS Scientific Production Unity "Ecran". 1997. - p. 248. sb1-2e.htm
- Shironosov
V.G. About the steady in unsteadness conditions, bifurcation, chaos of the nonlinear
dynamics systems. SA USSR,1990, v. 314, N 2, p. 316-320. sb22e.htm
- Shironosov
V.G. An addition of two magnetic difields with the due regard of spin motion equations.
Sel. Physics, 1985, N 7, p. 74-78. sb22e.htm
- Shironosov V.G. Fireball's physical nature. In collection thesises of articles
IV Russian university academical scientific practical conferention Izhevsk: publucation
of Udmurt state university, 1999, v.7, p. 55-58. sb15-9e.htm
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